I'm annoyed that I won't be able to play the return leg because of the booking I got at the end of the game.
Vinicius has had less time than Ajax's Frenkie de Jong, with only six starts in La Liga and one in the Champions League, but his impact has been arguably just as dramatic, the hype around the Brazilian already comparable.
However, Asensio converted the victor when he met a stunning delivery from Dani Carvajal at the far post.
Solari, in charge of Real Madrid B at the time, was the coach that received him, witnessing first-hand as the 18-year-old scored twice against Atletico B, curled in a free-kick against Unionistas and equalised against Celta Vigo B. "Not only the goal, which of course was very important for us".
Ajax were level with 15 minutes remaining as Neres broke free down the left before cutting the ball back for Ziyech, who slotted into the bottom corner. You have to know how to read games and we did that.
Real head into the match full of confidence after a 3-1 win in the Madrid derby at the weekend, which was their sixth victory in a seven-game unbeaten run in all competitions.
"Amazing atmosphere. I congratulate the fans and this team, who play very good football and with a lot of personality", he said.
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He also praised VAR which stopped Ajax going ahead when Tagliafico's goal was ruled out.
"I'm particularly happy with his goal and his performance", Solari said afterwards in his press conference.
Kasper Dolberg came close to levelling again in stoppage time, but Courtois stuck out a hand to block his effort as Madrid captain Sergio Ramos was made to work hard for the win in his 600th match for the club.
Vinicius beat Noussair Mazraoui on the left wing, cut inside, found Benzema and the French striker smashed home the opening goal.
Real goalkeeper Thibaut Courtois, whose blushes were spared by the VAR decision after his error led to the disallowed goal, felt the officials got it right.
Real Madrid coach Santiago Solari will have to decide between youth and experience as his side looks to take another step towards a historic fourth consecutive Champions League title on Wednesday.